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Approaching the Thermodynamic Limit of an Ideal Gas

Abstract

For a gas confined in a container, particle-wall interactions produce modifications to the partition function involving the average surface density of gas particles. While such correlations have a vanishing effect in the thermodynamic limit, examining them is beneficial for a sharper understanding of how the limit is attained. We contrast a classical and a quantum model of particle-wall correlations within the canonical ensemble.

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