Abstract
We derive an exact canonical matrix product state (MPS) representation for Dicke states |Dⁿ_k with minimal bond dimension χ=k+1, for general values of n and k, for which the W-state is the simplest case k=1. We use this MPS to formulate a quantum circuit for sequentially preparing Dicke states deterministically, relating it to the recursive algorithm of B\"artschi and Eidenbenz. We also find exact canonical MPS representations with minimal bond dimension for higher-spin and qudit Dicke states.