Abstract
We propose the use of parameter-free preentanglers as initial states for quantum algorithms. We apply this idea to the electronic structure problem, combining a quantized version of the Canonical Transformation by Yanai and Chan [J. Chem. Phys. 124, 194106 (2006)] with the Complete Active Space Density Matrix Renormalization Group. This new ansatz allows to shift the computational burden between the quantum and the classical processor. In the vicinity of multi-reference points in the potential energy surfaces of HO, N, BeH and the P4 system, we find this strategy to require significantly less parameters than corresponding generalized unitary coupled cluster circuits. We propose a new algorithm to prepare Matrix Product States based on the Linear Combination of Unitaries and compare it to the Sequential Unitary Algorithm proposed by Ran in [Phys. Rev. A 101, 032310 (2020)].