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Interseries transitions between Rydberg excitons in Cu2O

Abstract

We investigate the infrared optical transitions between excitons of the yellow, green and blue series in the cuprous oxide Cu₂O. We show that in many cases the dipole approximation is inadequate and, in particular, that it breaks down in yellow-blue transitions even for moderate principal quantum numbers of n ≈ 10. The interband matrix elements of the transition operator needed for the evaluation of the excitonic transition strengths are derived from known as well as from fitted band parameters.

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