Abstract
We study optically the coherent evolution of trions and excitons in a δ-doped 3.5 nm-thick ZnO/Zn_0.91Mg_0.09O multiple quantum well by means of time-resolved four-wave mixing at temperature of 1.5~K. Employing spectrally narrow picosecond laser pulses in the χ⁽³⁾ regime allows us to address differently localized trion and exciton states, thereby avoiding many-body interactions and excitation-induced dephasing. The signal in the form of photon echoes from the negatively charged A excitons (TA, trions) decays with coherence times varying from 8 up to 60~ps, depending on the trion energy: more strongly localized trions reveal longer coherence dynamics. The localized neutral excitons decay on the picosecond timescale with coherence times up to T₂=4.5~ps. The coherent dynamics of the XB exciton and TB trion are very short (T₂<1~ps), which is attributed to the fast energy relaxation from the trion and exciton B states to the respective A states. The trion population dynamics is characterized by the decay time T₁, rising from 30~ps to 100~ps with decreasing trion energy.