Abstract
Quantum communication over long distances is integral to information security and has been demonstrated in free space and fibre with two-dimensional polarisation states of light. Although increased bit rates can be achieved using high-dimensional encoding with spatial modes of light, the efficient detection of high-dimensional states remains a challenge to realise the full benefit of the increased state space. Here we exploit the entanglement between spatial modes and polarization to realise a four-dimensional quantum key distribution (QKD) protocol. We introduce a detection scheme which employs only static elements, allowing for the detection of all basis modes in a high-dimensional space deterministically. As a result we are able to realise the full potential of our high-dimensional state space, demonstrating efficient QKD at high secure key and sift rates, with the highest capacity-to-dimension reported to date. This work opens the possibility to increase the dimensionality of the state-space indefinitely while still maintaining deterministic detection and will be invaluable for long distance 'secure and fas' data transfer.