Abstract
As large language models (LLMs) are increasingly considered for automated assessment and feedback, understanding when LLM marking is valid is essential. We evaluate LLM-as-a-judge marking across three physics assessment formats - structured questions, written essays, and scientific plots - comparing GPT-5.2, Grok 4.1, Claude Opus 4.5, DeepSeek-V3.2, Gemini Pro 3, and committee aggregations against human markers under blind, solution-provided, false-solution, and anchored conditions. We distinguish absolute accuracy from rank-order agreement, since a marking system can match the distribution of human marks while failing to order responses by quality. Across task types, performance is sharply task-dependent. For blind university exam questions () and secondary and university structured questions (), models show robust rank-order agreement with human markers (Spearman ), with official solutions reducing error and strengthening agreement. False solutions degrade absolute accuracy, showing that models defer to provided references, but leave rank-ordering intact. Essay marking behaves fundamentally differently. Across scripts ( essays), blind AI marking is harsher and more variable than human marking and adding a mark scheme does not improve rank-order agreement. Anchored exemplars shift the AI mean close to the human mean and compress variance below the human standard deviation, but rank-order agreement remains near-zero. For code-based plot elements (), models achieve high rank-order agreement () with near-linear calibration. Across all task types, validity tracks the structure of the assessment task - the extent to which marks can be mapped to explicit, observable grading features - and the reliability of the human benchmark, rather than raw model capability.